Articles with "electrochemical surface" as a keyword



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Effect of chloride and pH on the electrochemical surface oxidation enhanced Raman scattering

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Published in 2019 at "Applied Surface Science"

DOI: 10.1016/j.apsusc.2018.12.148

Abstract: Abstract In the present work, electrochemical surface oxidation enhanced Raman scattering (EC-SOERS) was studied using time resolved Raman spectroelectrochemistry. This multiresponse technique allows us to obtain dynamic information about the processes taking place during the… read more here.

Keywords: enhanced raman; surface; oxidation; oxidation enhanced ... See more keywords
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Electrochemical surface plasmon resonance as a probe of redox reactions at the ionic liquid|gold interface

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Published in 2018 at "Journal of Electroanalytical Chemistry"

DOI: 10.1016/j.jelechem.2018.03.067

Abstract: Abstract Electrochemical surface plasmon resonance (ESPR) has been employed as a probe of redox reactions at the interface between gold (Au) and ionic liquid (IL). Two redox couples, ferrocene (Fc)/Fc+ and (ferrocenylmethyl)trimethylammonium (FTA+)/FTA2+, and two… read more here.

Keywords: probe redox; surface; redox; electrochemical surface ... See more keywords
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Computational Model for Electrochemical Surface-Enhanced Raman Scattering: Key Role of the Surface Charges and Synergy between Electromagnetic and Charge-Transfer Enhancement Mechanisms.

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Published in 2022 at "Journal of chemical theory and computation"

DOI: 10.1021/acs.jctc.2c00633

Abstract: We present a computational model for electrochemical surface-enhanced Raman scattering (EC-SERS). The surface excess of charge induced by the electrode potential (Vel) was introduced by applying an external electric field to a set of clusters… read more here.

Keywords: computational model; model electrochemical; charge; surface ... See more keywords
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Gravimetric, Electrochemical, Surface Morphology, DFT, and Monte Carlo Simulation Studies on Three N-Substituted 2-Aminopyridine Derivatives as Corrosion Inhibitors of Mild Steel in Acidic Medium

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Published in 2018 at "Journal of Physical Chemistry C"

DOI: 10.1021/acs.jpcc.8b02740

Abstract: Three N-substituted 2-aminopyridine derivatives, namely, 6-(2,4-dihydroxyphenyl)-4-phenyl-2-(phenylamino)nicotinonitrile (DPPN), 6-(2,4-dihydroxyphenyl)-2-((4-hydroxyphenyl)amino)-4-phenylnicotinonitrile (DHPN), and 6-(2,4-dihydroxyphenyl)-2-((4-methoxyphenyl)amino)-4-phenylnicotinonitrile (DMPN) were investigated for their inhibitive effects on mild steel corrosion in 1 M HCl solution using electrochemical, surface, chemical, and theoretical studies. Results… read more here.

Keywords: mild steel; three substituted; electrochemical surface; corrosion ... See more keywords
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Formamidine-Based Thiuram Disulfides as Efficient Inhibitors of Acid Corrosion of Mild Steel: Electrochemical, Surface, and Density Functional Theory/Monte Carlo Simulation Studies

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Published in 2022 at "ACS Omega"

DOI: 10.1021/acsomega.2c00985

Abstract: Electrochemical, surface, and density functional theory (DFT)/Monte Carlo (MC) simulation studies were used in investigating the characteristics of N,N′-(disulfanne-1,2-dicarbonothioyl)bis(N,N′-bis(2,6-dimethylphenyl)formimidamide) (DS1), N,N′-(disulfanne-1,2-dicarbonothioyl)bis(N,N′-bis(2,6-diisopropylphenyl)formimidamide) (DS2), N,N′-(disulfanne-1,2-dicarbonothioyl)bis(N,N′-dimesitylformimidamide) (DS3), and N,N′-(disulfanne-1,2-dicarbonothioyl)bis(N,N′-bis(2,6-dichlorophenyl)formimidamide) (DS4) as inhibitors of acid corrosion of mild steel.… read more here.

Keywords: functional theory; bis; steel; surface density ... See more keywords
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In situ electrochemical surface derivation of cobalt phosphate from a Co(CO3)0.5(OH)·0.11H2O nanoarray for efficient water oxidation in neutral aqueous solution.

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Published in 2017 at "Nanoscale"

DOI: 10.1039/c6nr09585b

Abstract: In this Communication, cobalt phosphate (Co-Pi) has been successfully developed on a Co(CO3)0.5(OH)·0.11H2O nanoarray (CCH NA) on Ti mesh in neutral phosphate-buffered solution (PBS) via in situ electrochemical surface derivation. The resulting core@shell structured CCH@Co-Pi… read more here.

Keywords: co3 11h2o; situ electrochemical; cobalt phosphate; 11h2o nanoarray ... See more keywords
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Electrochemical and Surface Investigation of Ni-Cr Glassy Alloys in Nitric Acid Solution

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Published in 2017 at "International Journal of Electrochemical Science"

DOI: 10.20964/2017.07.43

Abstract: To understand the corrosion and passivation behaviour of Ni70Cr21Si0.5B0.5P8C≤0.1Co≤1Fe≤1 (VZ1) and Ni72.65Cr7.3Si6.7B2.15C≤0.06Fe8.2Mo3 (VZ2) glassy alloys they were studied in nitric acid at different concentrations (1.012.0 M) by AC and DC techniques. Experimental investigations showed that… read more here.

Keywords: nitric acid; surface investigation; surface; electrochemical surface ... See more keywords
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An Electrochromic Ag-Decorated WO3−x Film with Adjustable Defect States for Electrochemical Surface-Enhanced Raman Spectroscopy

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Published in 2022 at "Nanomaterials"

DOI: 10.3390/nano12101637

Abstract: Electrochemical surface-enhanced Raman scattering (EC-SERS) spectroscopy is an ultrasensitive spectro-electrochemistry technique that provides mechanistic and dynamic information on electrochemical interfaces at the molecular level. However, the plasmon-mediated photocatalysis hinders the intrinsic electrochemical behavior of molecules… read more here.

Keywords: spectroscopy; surface enhanced; electrochemical surface; wo3 film ... See more keywords