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   Articles with "electrochemically mediated" as a keyword



Electrochemically-mediated amine regeneration of CO2 capture: From electrochemical mechanism to bench-scale visualization study

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recommendations! Published in 2021 at "Applied Energy"

DOI: 10.1016/j.apenergy.2021.117554

Abstract: Abstract Electrochemically-mediated amine regeneration (EMAR) is a new CO2 capture technology with the potential to exploit the excellent removal efficiencies of thermal amine scrubbers while reducing parasitic energy losses and capital costs. To achieve higher… read more here.

Keywords: mediated amine; co2; electrochemically mediated; study ... See more keywords

Electrochemically mediated reduction of epichlorohydrin pollutant by Ni(I)(hexamethylcyclam) in aqueous media

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recommendations! Published in 2017 at "Electrochimica Acta"

DOI: 10.1016/j.electacta.2017.02.147

Abstract: Abstract Epichlorohydrin (ECH) is a volatile organic compound and toxic to human health. Here we investigated clean mediated electrocatalytic dechlorination of ECH in aqueous solutions using electrogenerated [Nickel(I)(hexamethylcyclam)] + ([Ni(I)(hmc)] + ) at glassy carbon… read more here.

Keywords: hexamethylcyclam; epichlorohydrin; ech; dechlorination ... See more keywords

Electrochemically mediated precipitation of phosphate minerals for phosphorus removal and recovery: Progress and perspective.

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recommendations! Published in 2021 at "Water research"

DOI: 10.1016/j.watres.2021.117891

Abstract: Phosphorus (P) is an essential element for the growth and reproduction of organisms. Unfortunately, the natural P cycle has been broken by the overexploitation of P ores and the associated discharge of P into water… read more here.

Keywords: removal recovery; electrochemically mediated; recovery; water ... See more keywords

Toward Electrochemically Mediated Reversible Addition–Fragmentation Chain-Transfer (eRAFT) Polymerization: Can Propagating Radicals Be Efficiently Electrogenerated from RAFT Agents?

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recommendations! Published in 2019 at "Macromolecules"

DOI: 10.1021/acs.macromol.9b00112

Abstract: Electrochemistry provides easily tunable parameters for the preparation of well-defined polymers in a spatiotemporal controlled manner under mild conditions. This work discusses the requisites for an electrochemically mediated reversible addition–fragmentation chain-transfer (eRAFT) polymerization, in which… read more here.

Keywords: raft; electrochemically mediated; mediated reversible; reversible addition ... See more keywords

Electrochemically Mediated S-Glycosylation of 1-Thiosugars with Xanthene Derivatives.

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recommendations! Published in 2023 at "Organic letters"

DOI: 10.1021/acs.orglett.3c01185

Abstract: An efficient electrochemical dehydrogenative cross-coupling of benzylic C-H bonds with 1-thiosugars at room temperature is described. The direct S-glycosylation protocol avoids using any oxidant, which provides facile access to various glycosylated xanthene derivatives with up… read more here.

Keywords: electrochemically mediated; thiosugars xanthene; glycosylation; mediated glycosylation ... See more keywords

Redox-tunable isoindigos for electrochemically mediated carbon capture

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recommendations! Published in 2024 at "Nature Communications"

DOI: 10.1038/s41467-024-45410-z

Abstract: Efficient CO2 separation technologies are essential for mitigating climate change. Compared to traditional thermochemical methods, electrochemically mediated carbon capture using redox-tunable sorbents emerges as a promising alternative due to its versatility and energy efficiency. However,… read more here.

Keywords: carbon; carbon capture; mediated carbon; redox tunable ... See more keywords

Electrochemically mediated ATRP in ionic liquids: controlled polymerization of methyl acrylate in [BMIm][OTf]

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recommendations! Published in 2018 at "Polymer Chemistry"

DOI: 10.1039/c7py02134h

Abstract: Electrochemically mediated atom transfer radical polymerization (eATRP) of methyl acrylate (MA) was carried out for the first time in an ionic liquid, 1-butyl-3-methylimidazolium trifluoromethanesulfonate ([BMIm][OTf]). Ionic liquids are particularly suitable as solvents for eATRP because… read more here.

Keywords: electrochemically mediated; bmim otf; polymerization; methyl acrylate ... See more keywords

Scaling-Up an Aqueous Self-Degassing Electrochemically Mediated ATRP in Dispersion for the Preparation of Cellulose–Polymer Composites and Films

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recommendations! Published in 2022 at "Polymers"

DOI: 10.3390/polym14224981

Abstract: Electrochemically mediated atom transfer radical polymerization (eATRP) is developed in dispersion conditions to assist the preparation of cellulose-based films. Self-degassing conditions are achieved by the addition of sodium pyruvate (SP) as a ROS scavenger, while… read more here.

Keywords: electrochemically mediated; scaling aqueous; dispersion; preparation cellulose ... See more keywords