Transition metal catalyzed C-H functionalization through electrocatalysis.
Sign Up to like & getrecommendations! Published in 2023 at "ChemSusChem"
DOI: 10.1002/cssc.202202201
Abstract: Electrochemically promoted transition-metals catalyzed C-H functionalization has emerged as promising area of research over the last decades. However, development of this field is still at an early stage compared to the traditional functionalization reactions using… read more here.
Keywords: functionalization; catalyzed functionalization; metal catalyzed; electrochemically promoted ... See more keywords
Electrochemically promoted arylation of iodoaromatics
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Electroanalytical Chemistry"
DOI: 10.1016/j.jelechem.2017.05.034
Abstract: Abstract The electrochemical reduction of iodobenzene, 4-iodobenzonitrile and 4-iodonitrobenzene in DMF:benzene (2:8), in one-pot reaction and at room temperature, leads to cross-coupling products, biphenyl, 4-phenylbenzonitrile and 4-phenylnitrobenzene in low to moderate yields. The proposed mechanism… read more here.
Keywords: promoted arylation; arylation iodoaromatics; chemistry; reaction ... See more keywords
Electrochemically Promoted Fluoroalkylation-Distal Functionalization of Unactivated Alkenes.
Sign Up to like & getrecommendations! Published in 2019 at "Organic letters"
DOI: 10.1021/acs.orglett.9b00444
Abstract: Difunctionalization of olefins represents a powerful synthetic tool and yet a challenging task. This work describes an electrochemically enabled fluoroalkylation-migration reaction of unactivated olefins in the absence of a strong oxidant or heavy metal catalyst,… read more here.
Keywords: fluoroalkylation; fluoroalkylation distal; distal functionalization; functionalization unactivated ... See more keywords
Electrochemically Promoted Benzylation of [60]Fullerooxazolidinone
Sign Up to like & getrecommendations! Published in 2022 at "Nanomaterials"
DOI: 10.3390/nano12132281
Abstract: Benzylation of the electrochemically generated dianion from N-p-tolyl-[60]fullerooxazolidinone with benzyl bromide provides three products with different addition patterns. The product distribution can be dramatically altered by varying the reaction conditions. Based on spectral characterizations, these… read more here.
Keywords: benzylation; fullerooxazolidinone; promoted benzylation; electrochemically promoted ... See more keywords