Redox-Selective Macromolecular Electrolysis for Sequential Functionalization and Deconstruction.
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DOI: 10.1021/jacs.4c16333
Abstract: This study demonstrates that selective macromolecular electrolysis can be achieved on copolymers containing redox-orthogonal targets by controlling the externally applied voltage. We designed macromolecules containing phthalimide (E1/2 = -1.8 V vs Ag/AgNO3) and tetrachlorophthalimide (E1/2… read more here.
Keywords: redox selective; functionalization; electrolysis sequential; macromolecular electrolysis ... See more keywords