A 4H+/4e- Electron-Coupled-Proton Buffer Based on a Mononuclear Cu Complex.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c05454
Abstract: In this research article, we describe a 4H+/4e- electron-coupled-proton buffer (ECPB) based on Cu and a redox-active ligand. The protonated/reduced ECPB (complex 1: [Cu(8H+/14e-)]1+), consisting of CuI with 2 equiv of the ligand (catLH4: 1,1'-(4,5-dimethoxy-1,2-phenylene)bis(3-(tert-butyl)urea)),… read more here.
Keywords: coupled proton; electron coupled; proton buffer;
Using earth abundant materials for the catalytic evolution of hydrogen from electron-coupled proton buffers
Sign Up to like & getrecommendations! Published in 2017 at "Sustainable Energy and Fuels"
DOI: 10.1039/c7se00334j
Abstract: Hydrogen has a large array of uses throughout the chemical and energy industries, yet is largely produced through the reformation of fossil fuels. Renewable production of hydrogen, via electrolytic water splitting, could be key to… read more here.
Keywords: coupled proton; hydrogen; electron coupled; abundant materials ... See more keywords
Proton-electron-coupled functionalities of conductivity, magnetism, and optical properties in molecular crystals.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d1cc06826a
Abstract: Proton-electron-coupled reactions, specifically proton-coupled electron transfer (PCET), in biological and chemical processes have been extensively investigated for use in a wide variety of applications, including energy conversion and storage. However, the exploration of the functionalities… read more here.
Keywords: electron coupled; conductivity magnetism; proton electron; electron ... See more keywords
Spectral function of an electron coupled to hard-core bosons
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DOI: 10.1103/physrevb.102.035135
Abstract: The polaron, an electron dressed with HCB excitations, remains light even in the strong coupling limit as its effective mass remains of the order of the free electron mass. This result is in a sharp… read more here.
Keywords: spectral function; electron coupled; function electron; coupled hard ... See more keywords