Effect of synergistic interaction between Ce and Mn on the CO2 capture of calcium-based sorbent: Textural properties, electron donation, and oxygen vacancy
Sign Up to like & getrecommendations! Published in 2018 at "Chemical Engineering Journal"
DOI: 10.1016/j.cej.2017.09.198
Abstract: Abstract The diffusion of CO2 and mobility of O2− are the keys to capture of CO2 for CaO-based sorbents. We present a (Ce-Mn)-doped calcium-based sorbent, and investigate the effect of Ce and Mn incorporation on… read more here.
Keywords: calcium based; co2 capture; based sorbent; co2 ... See more keywords
Rewiring the “Push-Pull” Catalytic Machinery of a Heme Enzyme Using an Expanded Genetic Code
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DOI: 10.1021/acscatal.9b05129
Abstract: Nature employs a limited number of genetically encoded axial ligands to control diverse heme enzyme activities. Deciphering the functional significance of these ligands requires a quantitative understanding of how their electron-donating capabilities modulate the structures… read more here.
Keywords: pull; electron; electron donation; heme enzyme ... See more keywords
17O Electron Nuclear Double Resonance Analysis of Compound I: Inverse Correlation between Oxygen Spin Population and Electron Donation.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c05459
Abstract: Although the activation of inert C-H bonds by metal-oxo complexes has been widely studied, important questions remain, particularly regarding the role of oxygen spin population (i.e., unpaired electrons on the oxo ligand) in facilitating C-H… read more here.
Keywords: spin population; electron donation; oxygen spin; oxygen ... See more keywords