Ligand-Based Control of Nickel Catalysts: Switching Chemoselectivity from One-Electron to Two-Electron Pathways in Competing Reactions of 4-Halotetrahydropyrans.
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DOI: 10.1021/acs.orglett.2c01335
Abstract: Development of nickel-catalyzed transformations would be facilitated by an improved ability to predict which ligands promote and suppress competing mechanisms. We evaluate ligand-based modulation of catalyst preference for one- or two-electron pathways employing 4-halotetrahydropyrans as… read more here.
Keywords: nickel catalysts; ligand based; two electron; electron ... See more keywords