Reversible Two-Electron Redox Reactions Involving Tetralithio/Dilithio Palladole, Platinacycle, and Dicupra[10]annulene
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DOI: 10.1021/acs.organomet.9b00295
Abstract: The reaction chemistry of metalla-aromatics is fundamentally interesting. In this work, we find that tetralithio spiroaromatic palladole and platinacycle complexes 1 undergo selective two-electron oxidation with 1,2-dibromoethane as a mild oxidant, affording their corresponding dilithio… read more here.
Keywords: dicupra annulene; palladole platinacycle; electron redox; reversible two ... See more keywords
Three-Electron Redox Enabled Dithiocarboxylate Electrode for Superior Lithium Storage Performance.
Sign Up to like & getrecommendations! Published in 2018 at "ACS applied materials & interfaces"
DOI: 10.1021/acsami.8b11485
Abstract: Organic carboxyl compounds are promising anode candidates for lithium ion batteries in which oxygen-related redox dominates the reaction mechanisms. Herein, two nanostructured organic electrodes of π-extended naphthyl-based dicarboxylate and dithiocarboxylate compounds, namely sodium naphthalene-2,6-dicarboxylate (SND)… read more here.
Keywords: redox enabled; enabled dithiocarboxylate; redox; three electron ... See more keywords
Antioxidant action of persulfides and polysulfides against free radical-mediated lipid peroxidation
Sign Up to like & getrecommendations! Published in 2022 at "Free Radical Research"
DOI: 10.1080/10715762.2023.2165918
Abstract: Abstract Hydrogen sulfide, hydropersulfides, and hydropolysulfides have been revealed to play important physiological roles such as cell signaling and protection against oxidative stress, but the underlying mechanisms and dynamics of action remain elusive. It is… read more here.
Keywords: lipid peroxidation; peroxidation; free radical; plasma lipid ... See more keywords