Articles with "electron reduction" as a keyword



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Electron reduction for the preparation of rGO with high electrochemical activity

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Published in 2019 at "Catalysis Today"

DOI: 10.1016/j.cattod.2019.02.007

Abstract: Abstract A novel “electron reduction” initiated by dielectric barrier discharge (DBD) plasma, has been developed and employed for the reduction of graphene oxide. The “electron reduction” is operated at atmospheric pressure and relatively low gas… read more here.

Keywords: electron reduction; reduction; rgo; electrochemical activity ... See more keywords
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Interactions of the antioxidant enzymes NAD(P)H: Quinone oxidoreductase 1 (NQO1) and NRH: Quinone oxidoreductase 2 (NQO2) with pharmacological agents, endogenous biochemicals and environmental contaminants.

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Published in 2021 at "Chemico-biological interactions"

DOI: 10.1016/j.cbi.2021.109574

Abstract: NAD(P)H Quinone Oxidoreductase 1 (NQO1) is an antioxidant enzyme that catalyzes the two-electron reduction of several different classes of quinone-like compounds (quinones, quinone imines, nitroaromatics, and azo dyes). One-electron reduction of quinone or quinone-like metabolites… read more here.

Keywords: quinone oxidoreductase; nad quinone; electron reduction; oxidoreductase ... See more keywords
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Bifunctional template-mediated synthesis of porous ordered g-C3N4 decorated with potassium and cyano groups for effective photocatalytic H2O2 evolution from dual-electron O2 reduction

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Published in 2022 at "Chemical Engineering Journal"

DOI: 10.1016/j.cej.2021.132032

Abstract: Abstract The photocatalytic method to produce hydrogen peroxide (H2O2) as a substitute for fossil fuels has become a hot research topic. We herein propose cyano defect and potassium intercalation modified g-C3N4 photocatalysts in which the… read more here.

Keywords: potassium; electron reduction; dual electron; reduction ... See more keywords
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Interaction of Quinone-Related Electron Acceptors with Hydropersulfide Na2S2: Evidence for One-Electron Reduction Reaction.

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Published in 2019 at "Chemical research in toxicology"

DOI: 10.1021/acs.chemrestox.8b00158

Abstract: We previously reported that 9,10-phenanthraquinone (9,10-PQ), an atmospheric electron acceptor, undergoes redox cycling with dithiols as electron donors, resulting in the formation of semiquinone radicals and monothiyl radicals; however, monothiols have little reactivity. Because persulfide… read more here.

Keywords: electron reduction; one electron; electron acceptors; reaction ... See more keywords
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Catalytic Four-Electron Reduction of Dioxygen by Ferrocene Derivatives with a Nonheme Iron(III) TAML Complex.

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Published in 2020 at "Inorganic chemistry"

DOI: 10.1021/acs.inorgchem.0c02400

Abstract: A mononuclear nonheme iron(III) complex with a tetraamido macrocyclic ligand (TAML), [(TAML)FeIII]- (1), is a selective precatalyst for four-electron reduction of dioxygen by ferrocene derivatives in the presence of acetic acid (CH3COOH) in acetone. This… read more here.

Keywords: four electron; electron reduction; ferrocene derivatives; taml ... See more keywords
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Construction of Porous Tubular In2S3@In2O3 with Plasma Treatment-Derived Oxygen Vacancies for Efficient Photocatalytic H2O2 Production in Pure Water Via Two-Electron Reduction.

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Published in 2021 at "ACS applied materials & interfaces"

DOI: 10.1021/acsami.1c02953

Abstract: Tubular In2O3 was fabricated by the annealing of In-MIL-68 and further treated by Ar plasma to yield oxygen vacancies (Ov) followed by the growth of In2S3 nanoflowers. Unexpectedly, the resulting porous In2S3@In2O3 composites were discovered… read more here.

Keywords: in2o3; production; electron reduction; two electron ... See more keywords
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Viologen/Bromide Dual-Redox Electrochemical Capacitor with Two-Electron Reduction of Viologen.

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Published in 2019 at "ACS applied materials & interfaces"

DOI: 10.1021/acsami.9b10860

Abstract: In this work, we report a novel dual-redox electrochemical capacitor (EC) using a modified viologen (V) as anolyte and bromide (Br) as catholyte. In general, modified viologens are dications. When they are used as anolyte… read more here.

Keywords: dual redox; redox; viologen; electron reduction ... See more keywords
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Selective Nitrate-to-Ammonia Transformation on Surface Defects of Titanium Dioxide Photocatalysts

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Published in 2017 at "ACS Catalysis"

DOI: 10.1021/acscatal.7b00611

Abstract: Ammonia (NH3) is an essential chemical in modern society, currently manufactured via the Haber–Bosch process with H2 and N2 under extremely high pressure (>200 bar) and high-temperature conditions (>673 K). Toxic nitrate anion (NO3–) contained… read more here.

Keywords: reduction; electron reduction; surface; surface defects ... See more keywords
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Waste Recycling: Ionic Liquid-Catalyzed 4-Electron Reduction of CO2 with Amines and Polymethylhydrosiloxane Combining Experimental and Theoretical Study

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Published in 2018 at "ACS Sustainable Chemistry & Engineering"

DOI: 10.1021/acssuschemeng.8b02352

Abstract: The acetate-based ionic liquids (ILs), e.g., [nBu4N]OAc, have been developed for challenging 4-electron reduction of CO2 with amines and hydrosilane to afford aminals. Notably, polymethylhydrosiloxane, a cheap byproduct of the silicone industry, also works well… read more here.

Keywords: electron reduction; reduction co2; study; electron ... See more keywords
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Photoredox generation of the trifluoromethyl radical from borate complexes via single electron reduction.

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Published in 2018 at "Chemical communications"

DOI: 10.1039/c8cc00245b

Abstract: A method for the generation of the CF3 radical from CF3-substituted borate complexes bearing a pyridine-N-oxide ligand is described. Cleavage of the C-B bond occurs via single electron reduction by a Cu(i) photocatalyst activated by… read more here.

Keywords: single electron; electron reduction; generation; via single ... See more keywords
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A poorly soluble organic electrode material for high energy density lithium primary batteries based on a multi-electron reduction.

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Published in 2021 at "Chemical communications"

DOI: 10.1039/d1cc03938e

Abstract: Here we report an organic cathode material with poor solubility for lithium primary batteries, i.e. indeno[3,2-b]fluorene-6,12-dione. Each carbonyl group experiences a four-electron reduction to a methylene group, resulting in a high energy density of 1392… read more here.

Keywords: electron reduction; high energy; primary batteries; organic electrode ... See more keywords