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Studies on the Enantioselective Iminium Ion Trapping of Radicals Triggered by an Electron-Relay Mechanism

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Published in 2017 at "Journal of the American Chemical Society"

DOI: 10.1021/jacs.7b01446

Abstract: A combination of electrochemical, spectroscopic, computational, and kinetic studies has been used to elucidate the key mechanistic aspects of the previously reported enantioselective iminium ion trapping of photochemically generated carbon-centered radicals. The process, which provides… read more here.

Keywords: electron relay; ion trapping; enantioselective iminium; iminium ion ... See more keywords