Electron Relay Boosts Ruthenium‐Laccase System Photo‐Epoxidation
Sign Up to like & getrecommendations! Published in 2025 at "ChemCatChem"
DOI: 10.1002/cctc.202501086
Abstract: We report here the light‐driven oxidation of olefin to epoxide using a [Ru(bipyridine)3]2+/laccase (RuII/LAC3)‐based system, enhanced by the presence of methyl viologen (MV2+) as an electron relay. This approach leads to a fivefold increase in… read more here.
Keywords: electron relay; laccase; system; epoxidation ... See more keywords
Fluorenone-Based COFs with Electron-Relay Function for Highly Efficient Photocatalytic Uranium Extraction from Wastewater.
Sign Up to like & getrecommendations! Published in 2025 at "ACS applied materials & interfaces"
DOI: 10.1021/acsami.5c21083
Abstract: The remediation of uranium-contaminated wastewater is crucial, given the severe environmental and health risks associated with uranium's chemical toxicity and radioactivity. Photocatalytic reduction of soluble U(VI) to insoluble U(IV) represents a promising strategy, yet its… read more here.
Keywords: wastewater; uranium; electron relay; fluorenone based ... See more keywords
Studies on the Enantioselective Iminium Ion Trapping of Radicals Triggered by an Electron-Relay Mechanism
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DOI: 10.1021/jacs.7b01446
Abstract: A combination of electrochemical, spectroscopic, computational, and kinetic studies has been used to elucidate the key mechanistic aspects of the previously reported enantioselective iminium ion trapping of photochemically generated carbon-centered radicals. The process, which provides… read more here.
Keywords: electron relay; ion trapping; enantioselective iminium; iminium ion ... See more keywords