Tailoring Noncovalent Interactions to Activate Persistent Room‐Temperature Phosphorescence from Doped Polyacrylonitrile Films
Sign Up to like & getrecommendations! Published in 2021 at "Advanced Functional Materials"
DOI: 10.1002/adfm.202101656
Abstract: Organic phosphors exhibiting room‐temperature phosphorescence (RTP) in amorphous phase are good candidates for optoelectronic and biomedical applications. In this proof‐of‐concept work, a rational strategy to activate wide‐color ranged and persistent RTP from amorphous films by… read more here.
Keywords: temperature phosphorescence; electron rich; room temperature; pan ... See more keywords
Electron-Rich Nanorelay Enhances Ligand-to-Metal Charge Transfer in Lanthanide Metal-Organic Frameworks during Photocatalytic CO2 Conversion.
Sign Up to like & getrecommendations! Published in 2025 at "Advanced materials"
DOI: 10.1002/adma.202512763
Abstract: Lanthanide metal-organic frameworks (Ln-MOFs) exhibit potential yet limitations for photocatalytic CO2 conversion. Their "potential" stems from their CO2 adsorption capability, attributed to the ligand-field effects and specialized pore microenvironments; the "limitation" is due to the… read more here.
Keywords: electron rich; photocatalytic co2; metal; co2 conversion ... See more keywords
Activation of Molecular Oxygen by Electron-Rich Materials for Sustainable Soil Remediation.
Sign Up to like & getrecommendations! Published in 2025 at "Advanced science"
DOI: 10.1002/advs.202518117
Abstract: Traditional advanced oxidation processes (AOPs) in soil remediation rely on external chemical oxidants, which have evident drawbacks of high cost, soil structure disruption, and high carbon footprint. Compared to traditional AOPs, molecular oxygen (O2) activation… read more here.
Keywords: electron rich; activation; soil; rich materials ... See more keywords
Unexpected One‐Pot Synthesis of Diindolotriazatruxene: A Planar Electron‐Rich Scaffold Toward Highly π‐Extended PAHs
Sign Up to like & getrecommendations! Published in 2017 at "Asian Journal of Organic Chemistry"
DOI: 10.1002/ajoc.201700498
Abstract: A unique planar and highly π-extended scaffold, 3,8,14,19-tetrabromo-diindolotriazatruxene (4Br-DIT), was synthesized for the first time by a facile one-pot strategy. The structure of 4Br-DIT was adequately verified by MALDI-TOF mass spectrometry, 1H and 13C NMR,… read more here.
Keywords: planar; electron rich; highly extended; diindolotriazatruxene ... See more keywords
Electron-Rich π-Extended Diindolotriazatruxene-Based Chemosensors with Highly Selective and Rapid Responses to Nitroaromatic Explosives.
Sign Up to like & getrecommendations! Published in 2019 at "ChemPlusChem"
DOI: 10.1002/cplu.201900347
Abstract: A series of electron-rich π-extended diindolotriazatruxene-based compounds DIT, 4Py-DIT (bearing pyrene units) and 4PyF-DIT (bearing fluorene units) have been explored and investigated as fluorescence chemosensors. Quantitative analysis through fluorescence titrations showed that the resulting DIT… read more here.
Keywords: highly selective; electron rich; diindolotriazatruxene based; fluorescence ... See more keywords
Photoinduced Intermolecular Hydroamination and Hydroetherification of Electron-rich Alkenes with Low Catalyst Loadings.
Sign Up to like & getrecommendations! Published in 2024 at "ChemSusChem"
DOI: 10.1002/cssc.202301511
Abstract: A photochemical method based on visible-light irradiation (blue LEDs/sunlight) has been developed for the intermolecular hydroamination and hydroetherification of electron-rich alkenes. This photochemical method is compatible with a wide range of azoles and electron-rich alkenes,… read more here.
Keywords: rich alkenes; electron rich; hydroamination hydroetherification; intermolecular hydroamination ... See more keywords
Oxidative cyclization of 5-aryl-1-benzyl-1,2,3-triazoles bearing electron-rich aromatic groups: ortho/ortho and ortho/ipso coupling
Sign Up to like & getrecommendations! Published in 2021 at "Chemistry of Heterocyclic Compounds"
DOI: 10.1007/s10593-021-02985-5
Abstract: The intramolecular oxidative coupling of electron-rich aromatic groups in 5-(het)aryl-1-(het)arylalkyl-1H-1,2,3-triazoles was studied in detail. Under treatment with phenyliodoso bis(trifluoroacetate) and boron trifluoride etherate these substrates afforded products of either ortho/ortho or ortho/ipso coupling depending on… read more here.
Keywords: electron rich; ortho ortho; ortho; aromatic groups ... See more keywords
Electron-rich platinum electrocatalysts supported onto tin oxides for efficient oxygen reduction
Sign Up to like & getrecommendations! Published in 2021 at "Composites Communications"
DOI: 10.1016/j.coco.2020.100603
Abstract: Abstract Developing high-performance electrocatalysts for the oxygen reduction reaction (ORR) is of significance for metal-air batteries and fuel cells. The platinum (Pt) catalyst is considered as the most ideal candidate for its highest catalytic activity… read more here.
Keywords: catalyst; rich platinum; electron rich; oxygen reduction ... See more keywords
Electron-rich functional doping carbon host as dendrite-free lithium metal anode
Sign Up to like & getrecommendations! Published in 2018 at "Electrochimica Acta"
DOI: 10.1016/j.electacta.2018.07.161
Abstract: Abstract The Li metal anode has been regarded as the ultimate anode because of high theoretical capacity and low potential. Unfortunately, dendrite growth and safety issues impede its practical applications. Herein, we report a series… read more here.
Keywords: electron rich; anode; lithium; host ... See more keywords
Electrochemical access to aryl sulfides from aryl thiols and electron-rich arenes with the potassium iodide as a mediator
Sign Up to like & getrecommendations! Published in 2020 at "Electrochimica Acta"
DOI: 10.1016/j.electacta.2019.135371
Abstract: Abstract An indirect electrooxidation method catalyzed by potassium iodide at a low potential for the synthesis of aryl sulfides from aryl thiols and electron-rich arenes has been developed. Cyclic voltammetry was carried out to investigate… read more here.
Keywords: aryl thiols; electron rich; rich arenes; aryl sulfides ... See more keywords
Luminescence and structure regulation of graphitic carbon nitride by electron rich P ions doping
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Luminescence"
DOI: 10.1016/j.jlumin.2020.117616
Abstract: Abstract Graphitic carbon nitride (g-C3N4) modified with electron rich P ions was synthesized by directly heating a mixture of melamine and diammonium hydrogenphosphate with various doping concentration. The effect of the doping ion and its… read more here.
Keywords: electron rich; rich ions; graphitic carbon; luminescence ... See more keywords