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Published in 2021 at "Archive for Rational Mechanics and Analysis"
DOI: 10.1007/s00205-021-01700-0
Abstract: We consider the limit of vanishing Debye length for ionic diffusion in fluids, described by the Nernst-Planck-Navier-Stokes system. In the asymptotically stable cases of blocking (vanishing normal flux) and uniform selective (special Dirichlet) boundary conditions…
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Keywords:
planck navier;
boundary conditions;
electroneutrality;
nernst planck ... See more keywords
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Published in 2021 at "Physical review. E"
DOI: 10.1103/physreve.104.044803
Abstract: The electrostatic screening of charge in one-dimensional confinement leads to long-range breakdown in electroneutrality within a nanopore. Through a series of continuum simulations, we demonstrate the principles of electroneutrality breakdown for electrolytes in one-dimensional confinement.…
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Keywords:
nanopore arrays;
breakdown nanopore;
electroneutrality breakdown;
confinement ... See more keywords
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Published in 2025 at "Journal of The Electrochemical Society"
DOI: 10.1149/1945-7111/add185
Abstract: Phase electroneutrality is a near-omnipresent assumption in electrochemical reactions. Even media such as biphasic oil-water interfaces and kinetically stable emulsions follow this “rule.” This implies all electron transfer reactions must be accompanied by ion transfer…
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Keywords:
electron transfer;
electroneutrality;
phase electroneutrality;
electrochemical processes ... See more keywords