Electronic chirality inversion of lanthanide complex induced by achiral molecules
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DOI: 10.1038/s41598-018-34790-0
Abstract: A novel mechanism for chiroptical activity inversion based on the electronic structure of metal complexes without Λ- or Δ-type structure change was demonstrated spectroscopically and theoretically. To demonstrate the mechanism, a europium (Eu(III)) complex with… read more here.
Keywords: inversion; achiral molecules; structure; iii complex ... See more keywords