Enhanced resistance to poisoning of Pd in alkynes semi‐hydrogenation by metal–ligand electronic interactions
Sign Up to like & getrecommendations! Published in 2024 at "AIChE Journal"
DOI: 10.1002/aic.18687
Abstract: Given that the retention of nitrogen readily renders active site poisoning, designing versatile catalysts characterized by notable selectivity and even resistance to poisoning for alkyne semi‐hydrogenation under nitrogen‐containing conditions is considerably challenging. In this article,… read more here.
Keywords: hydrogenation; ligand electronic; resistance poisoning; semi hydrogenation ... See more keywords
Maximizing dopant photoluminescence in co-doped semiconductor nanoparticles for multiplex assays by tuning inter dopant electronic interactions: Synthetic co-doping or physical mixing of singly doped moieties?
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Luminescence"
DOI: 10.1016/j.jlumin.2018.06.042
Abstract: Abstract Evaluation of inter dopant electronic interactions is important to maximize photoluminescence for their use as multiplex assays. This work compares the photophysical properties of lanthanide dopants in cases where the lanthanide moieties have been… read more here.
Keywords: inter; emission; inter dopant; electronic interactions ... See more keywords
Synthesis and intramolecular electronic interactions of hexaarylbenzene bearing redox-active Cp*(dppe)Fe-C≡C- termini
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Organometallic Chemistry"
DOI: 10.1016/j.jorganchem.2018.10.002
Abstract: Abstract Hexaphenyl- (1) and hexathienyl-benzene (2) complexes with the six redox-active Cp*(dppe)Fe-C≡C- units are synthesized and their properties in terms of molecular junction are investigated. Both complexes show stepwise multi-redox processes and IVCT bands in… read more here.
Keywords: electronic interactions; active dppe; intramolecular electronic; redox active ... See more keywords
Sensitive Raman Probe of Electronic Interactions between Monolayer Graphene and Substrate under Electrochemical Potential Control
Sign Up to like & getrecommendations! Published in 2018 at "ACS Omega"
DOI: 10.1021/acsomega.7b01928
Abstract: In situ electrochemical Raman spectroscopic measurements of defect-free monolayer graphene on various substrates were performed under electrochemical potential control. The G and 2D Raman band wavenumbers (ωG, ω2D) of graphene were found to depend upon… read more here.
Keywords: raman; monolayer graphene; electronic interactions; potential control ... See more keywords
Modulating the Electronic Interactions via Heterostructure Engineering for Energy-Saving Hydrogen Production at High Current Densities
Sign Up to like & getrecommendations! Published in 2024 at "Journal of Materials Chemistry A"
DOI: 10.1039/d4ta07348g
Abstract: The advanced alkaline hydrogen evolution reaction (HER) catalysts should have low water dissociation energy barrier and fast reaction kinetics. However, the single component transition metal catalysts usually show insufficient activation... read more here.
Keywords: energy; via heterostructure; modulating electronic; interactions via ... See more keywords
Electronic interactions of a quatertiophene-based surfactant at the liquid/gas interface.
Sign Up to like & getrecommendations! Published in 2025 at "Soft matter"
DOI: 10.1039/d5sm00122f
Abstract: We report the synthesis of a functional molecule, a quatertiophene-based surfactant, which can both adsorb at the water/gas interface (surface active molecule) and aggregate through π-π stacking interactions. We assess then the ability of this… read more here.
Keywords: based surfactant; quatertiophene based; gas interface; electronic interactions ... See more keywords