Electronic Interplay between TTF and Extended-TCNQ Electrophores along a Ruthenium Bis(acetylide) Linker.
Sign Up to like & getrecommendations! Published in 2017 at "Organic letters"
DOI: 10.1021/acs.orglett.7b02818
Abstract: A bis(TTF-butadiynyl) ruthenium D-D'-D complex, with intramolecular electronic interplay between the three electron-donating electrophores, was easily converted through a cycloaddition-retroelectrocyclization with TCNQ into a D-A-D'-A-D pentad complex, which exhibits an intense intramolecular charge transfer together… read more here.
Keywords: ruthenium; interplay ttf; interplay; electronic interplay ... See more keywords
Complex electronic interplay of σ-hole and π-hole interactions in crystals of halogen substituted 1,3,4-oxadiazol-2(3H)-thiones
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DOI: 10.1039/c7ce00678k
Abstract: In this study, we have performed a detailed analysis of the nature and strength of different intermolecular interactions present in the crystal structures of four biologically active derivatives of 1,3,4-oxadiazol-2(3H)-thiones. The study was primarily focused… read more here.
Keywords: oxadiazol thiones; hole; complex electronic; electronic interplay ... See more keywords
Electronic interplay: synergism of binary transition metals and role of M-N-S site towards oxygen electrocatalysis.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d1cc06050c
Abstract: Towards rational catalyst development, a binary Fe-Co centre has been coordinated with S and N in a nanocarbon matrix. An electronic drift between Fe-Co and an extended +R effect from the S dopants towards the… read more here.
Keywords: synergism binary; binary transition; electronic interplay; interplay synergism ... See more keywords