Articles with "electronic metal" as a keyword



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Self‐Accommodation Induced Electronic Metal–Support Interaction on Ruthenium Site for Alkaline Hydrogen Evolution Reaction

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Published in 2023 at "Advanced Materials"

DOI: 10.1002/adma.202301369

Abstract: Tuning the metal‐support interaction of supported metal catalysts has been found to be the most effective approach to modulating electronic structure and improving catalytic performance. But practical understanding of the charge transfer mechanism at the… read more here.

Keywords: alkaline hydrogen; metal support; support interaction; electronic metal ... See more keywords
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Electronic Metal-Support Interaction Directing the Design of Fe(III)-Based Catalysts for Efficient Advanced Oxidation Processes by Dual Reaction Paths.

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Published in 2022 at "Small"

DOI: 10.1002/smll.202203269

Abstract: Persistent organic pollutants (POPs) have a huge impact on human health due to their high toxicity and non-degradability. It is still of great difficulty to develop highly efficient catalysts toward the degradation of POPs. Herein,… read more here.

Keywords: metal support; support interaction; iii; electronic metal ... See more keywords
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Electronic Metal-Support Interaction Triggering Interfacial Charge Polarization over CuPd/N-Doped-C Nanohybrids Drives Selectively Electrocatalytic Conversion of Nitrate to Ammonia.

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Published in 2022 at "Small"

DOI: 10.1002/smll.202203335

Abstract: Selective electrocatalytic nitrate-to-ammonia conversion holds significant potential in treatment of nitrate wastewater and simultaneously produces high-value-added ammonia. However, today's development of nitrate-to-ammonia technology remains hindered by the lack of electrocatalysts with high activity and selectivity.… read more here.

Keywords: nitrate ammonia; cupd; nitrate; electronic metal ... See more keywords
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Electronic Metal–Support Interaction Modulation of Single‐Atom Electrocatalysts for Rechargeable Zinc–Air Batteries

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Published in 2022 at "Small Methods"

DOI: 10.1002/smtd.202100947

Abstract: High‐performance oxygen electrocatalysts play a key role in the widespread application of rechargeable Zn–air batteries (ZABs). Single‐atom catalysts (SACs) with maximum atom efficiency and well‐defined active sites have been recognized as promising alternatives of the… read more here.

Keywords: air batteries; metal support; single atom; support interaction ... See more keywords
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Engineering stable Pt nanoparticles and oxygen vacancies on defective TiO2 via introducing strong electronic metal-support interaction for efficient CO2 photoreduction

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Published in 2020 at "Chemical Engineering Journal"

DOI: 10.1016/j.cej.2019.123450

Abstract: Abstract This work for the first time reports the promoting effect of strong electronic metal-support interaction (EMSI) in Pt/TiO2-VO (VO: oxygen vacancy) for gas-phase CO2 photoreduction. A novel in-situ surface hydrogenation was developed to prepare… read more here.

Keywords: tio2; strong electronic; metal support; oxygen vacancies ... See more keywords
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Understanding the electronic metal-support interactions of the supported Ni cluster for the catalytic hydrogenation of ethylene

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Published in 2021 at "Molecular Catalysis"

DOI: 10.1016/j.mcat.2021.111731

Abstract: Abstract The electronic metal-support interaction (EMSI) has a very profound impact on the catalytic activity of supported catalysts. In this paper, density functional theory calculations were utilized to understand the effect of EMSI between Ni… read more here.

Keywords: ethylene; metal support; support; electronic metal ... See more keywords
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Boosting Toluene Combustion by Tuning Electronic Metal-Support Interactions in In Situ Grown Pt@Co3O4 Catalysts.

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Published in 2021 at "Environmental science & technology"

DOI: 10.1021/acs.est.1c07016

Abstract: Electronic metal-support interaction (EMSI) has attracted great attention in volatile organic compound (VOC) abatement. Herein, Pt@Co3O4 catalysts were prepared via a metal-organic framework (MOF) in situ growth approach to boost toluene degradation. The partial electron… read more here.

Keywords: co3o4 catalysts; co3o4; electronic metal; toluene combustion ... See more keywords
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Enhanced Catalytic Ozonation for Eliminating CH3SH via Stable and Circular Electronic Metal-Support Interactions of Si-O-Mn Bonds with Low Mn Loading.

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Published in 2022 at "Environmental science & technology"

DOI: 10.1021/acs.est.1c07065

Abstract: Catalytic ozonation of methyl mercaptan (CH3SH) can effectively control this unbearable odorous sulfur-containing volatile organic compound (S-VOC). The construction of an electronic metal-support interaction (EMSI) coordination structure to maximize the number of active sites and… read more here.

Keywords: electronic metal; catalytic ozonation; ozonation; metal support ... See more keywords
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Electronic Metal–Support Interactions in the Activation of CO Oxidation over a Cu/TiO2 Aerogel Catalyst

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Published in 2020 at "Journal of Physical Chemistry C"

DOI: 10.1021/acs.jpcc.0c06026

Abstract: Carbon monoxide (CO) oxidation is not only an important industrial reaction but also a useful model system for investigations into reaction dynamics involving new catalyst designs. In this work, we... read more here.

Keywords: interactions activation; oxidation; metal support; support interactions ... See more keywords
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Ni-O4 as Active Sites for Efficient Oxygen Evolution Reaction with Electronic Metal-Support Interactions.

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Published in 2022 at "ACS applied materials & interfaces"

DOI: 10.1021/acsami.2c11201

Abstract: Precise adjustment of the metal site structure in single-atom catalysts (SACs) plays a key role in addressing the oxygen evolution reaction (OER). Herein, we report the synthesis of O-doped Ni SACs anchored on porous graphene-like… read more here.

Keywords: active sites; oxygen evolution; metal support; electronic metal ... See more keywords