Adjustment of electronic (OMe and NO2) and steric (CHPh2) effects in bis(imino)pyridinyliron precatalysts for producing high molecular weight linear PE
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DOI: 10.1002/ejic.202400380
Abstract: Based on variations in steric and electronic substituents in the N‐aryl unit, a set of five 2‐[1‐(arylimino)ethyl]‐6‐[1‐(2‐benzhydryl‐4‐nitro‐6‐methoxyphenylimino)ethyl]pyridyliron dichloride complexes, revealing a distorted square pyramidal geometry around the iron center. When activated in situ with MAO… read more here.
Keywords: iron; high molecular; molecular weight; electronic ome ... See more keywords