A resorcinarene for inhibition of Aβ fibrillation† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c6sc04854d Click here for additional data file.
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DOI: 10.1039/c6sc04854d
Abstract: Low toxic resorcinarene can effectively inhibit Aβ fibrillation and delay the formation of toxic Aβ 42 species. read more here.
Keywords: fibrillation; fibrillation electronic; resorcinarene; inhibition fibrillation ... See more keywords
Lithium ions solvated in helium† †Electronic supplementary information (ESI) available: Radial distributions of HenLi+ snowballs. See DOI: 10.1039/c8cp04522d
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DOI: 10.1039/c8cp04522d
Abstract: We report on a combined experimental and theoretical study of Li+ ions solvated by up to 50 He atoms. read more here.
Keywords: ions solvated; helium electronic; lithium ions; supplementary information ... See more keywords
Oxidative steps during the biosynthesis of squalestatin S1† †Electronic supplementary information (ESI) available: All experimental procedures and analytical data. See DOI: 10.1039/c8sc02615g
Sign Up to like & getrecommendations! Published in 2019 at "Chemical Science"
DOI: 10.1039/c8sc02615g
Abstract: Two enzymes of previously unknown function encoded by the squalestatin biosynthetic gene cluster from the fungus Phoma MF5453 catalyse a remarkable series of six consecutive oxidations to form the 4,8-dioxa-bicyclo[3.2.1]octane core of the squalestatins. read more here.
Keywords: steps biosynthesis; oxidative steps; supplementary information; squalestatin electronic ... See more keywords
Supercooling of functional alkyl-π molecular liquids† †Electronic supplementary information (ESI) available: Experimental section, NMR, MALDI-TOF MS, additional figures and tables as indicated in the main text. See DOI: 10.1039/c8sc02723d
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DOI: 10.1039/c8sc02723d
Abstract: The formation of a metastable supercooled alkyl-π molecular liquid was prohibited by subtle alteration of the molecular structure. read more here.
Keywords: supercooling functional; functional alkyl; molecular liquids; alkyl molecular ... See more keywords
Asymmetric synthesis of (–)-naltrexone† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c8sc03748e
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DOI: 10.1039/c8sc03748e
Abstract: The asymmetric synthesis of (–)-naltrexone was achieved by a Rh(i)-catalyzed C–H alkenylation and torquoselective electrocyclization cascade and late-stage C–H hydroxylation. read more here.
Keywords: synthesis naltrexone; naltrexone electronic; electronic supplementary; asymmetric synthesis ... See more keywords
Construction of supramolecular nanotubes from protein crystals† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c8sc04167a
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DOI: 10.1039/c8sc04167a
Abstract: Cross-linking of protein crystals promotes disulfide-mediated nanotubes. read more here.
Keywords: crystals electronic; protein crystals; nanotubes protein; construction supramolecular ... See more keywords
Guest recognition enhanced by lateral interactions† †Electronic supplementary information (ESI) available. CCDC 1858887–1858890 and 1858892. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c9sc00591a
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DOI: 10.1039/c9sc00591a
Abstract: Lateral interactions enhance the guest inclusion and peripheral complexation within a highly charged covalent cage. read more here.
Keywords: recognition enhanced; lateral interactions; interactions electronic; enhanced lateral ... See more keywords
H-Bond donor parameters for cations† †Electronic supplementary information (ESI) available: Titration data and details of fitting the binding isotherm. See DOI: 10.1039/c9sc00721k
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DOI: 10.1039/c9sc00721k
Abstract: Parameters that provide a quantitative description of the free energy of interaction of cations with any H-bond acceptor in any solvent have been experimentally determined. read more here.
Keywords: parameters cations; bond donor; electronic supplementary; cations electronic ... See more keywords
Hydroalkynylative cyclization of 1,6-enynes with terminal alkynes† †Electronic supplementary information (ESI) available: CCDC 1845186 for 3m and 1847564 for 3p. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c9sc02341k
Sign Up to like & getrecommendations! Published in 2019 at "Chemical Science"
DOI: 10.1039/c9sc02341k
Abstract: A rhodium-catalyzed highly regio- and enantioselective hydroalkynylation generating cis-hydrobenzofuranone-tethered enynes has been developed. The reaction proceeds with a dynamic kinetic head-to-head insertion and symmetry breaking Michael addition cascade. read more here.
Keywords: alkynes electronic; enynes terminal; terminal alkynes; cyclization enynes ... See more keywords
Conceptual similarities between zeolites and artificial enzymes† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c9sc02477h
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DOI: 10.1039/c9sc02477h
Abstract: Inspired by artificial enzymes, we have designed zeolites acting as scaffolds for a given Diels–Alder reaction using mimics of the reaction transition state. read more here.
Keywords: similarities zeolites; conceptual similarities; artificial enzymes; enzymes electronic ... See more keywords