Electrophilic fluorination using PhIO/HF·THF reagent
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Fluorine Chemistry"
DOI: 10.1016/j.jfluchem.2020.109670
Abstract: Abstract New electrophilic fluorination reagent HF·THF/PhIO was introduced and tested on three general classes of compounds. Compared with the literature data reported for basic reagents, such as HF/TEA/PhIO and HF/Py/PhIO, the new reagent showed superior… read more here.
Keywords: reagent; using phio; fluorination; phio thf ... See more keywords
An efficient synthesis of fluoro-neplanocin A analogs using electrophilic fluorination and palladium-catalyzed dehydrosilylation
Sign Up to like & getrecommendations! Published in 2019 at "Organic Chemistry Frontiers"
DOI: 10.1039/c9qo00099b
Abstract: An alternative and efficient approach to neplanocin A analogs 1b and 1d has been developed using electrophilic fluorination and Pd-catalyzed dehydrosilylation. read more here.
Keywords: neplanocin analogs; using electrophilic; catalyzed dehydrosilylation; electrophilic fluorination ... See more keywords
A convenient access to fluorophosphonium triflate salts by electrophilic fluorination and anion exchange
Sign Up to like & getrecommendations! Published in 2021 at "Inorganic chemistry frontiers"
DOI: 10.1039/d1qi00322d
Abstract: The in situ one-pot electrophilic fluorination of phosphanes with NFSI followed by anion exchange with MeOTf gives highly electrophilic fluorophosphonium triflates – highly efficient catalysts for the synthesis of N-sulfonylamidines from amides. read more here.
Keywords: convenient access; anion exchange; fluorophosphonium; electrophilic fluorination ... See more keywords
Fluorocarbyne complexes via electrophilic fluorination of carbido ligands
Sign Up to like & getrecommendations! Published in 2023 at "Chemical Science"
DOI: 10.1039/d3sc00261f
Abstract: The new fluorocarbynes [M( Created by potrace 1.16, written by Peter Selinger 2001-2019 CF)(CO)2(Tp*)] (M = Mo, W; Tp* = tris(dimethylpyrazolyl)borate) arise from electrophilic fluorination of the lithiocarbynes [M(CLi)(CO)2(Tp*)] with FN(SO2Ph)2. The reactions of [W(CF)(CO)2(Tp*)]… read more here.
Keywords: 600 600; 600 40z; fluorocarbyne complexes; electrophilic fluorination ... See more keywords