α-Electrophilic Reactivity of Nitronates.
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DOI: 10.1002/tcr.201800009
Abstract: Chemistry of covalent nitronates regarding nucleophilic addition to C=N bond is described. Various types of electrophilic activation of nitronates and stability of formed products are discussed with main attention paid to authors' work in the… read more here.
Keywords: electrophilic reactivity; chemistry; reactivity nitronates;
A Mononuclear Non-heme Iron(III)-Peroxo Complex with an Unprecedented High O-O Stretch and Electrophilic Reactivity.
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DOI: 10.1021/jacs.1c03358
Abstract: A mononuclear non-heme iron(III)-peroxo complex, [Fe(III)(O2)(13-TMC)]+ (1), was synthesized and characterized spectroscopically; the characterization with electron paramagnetic resonance, Mössbauer, X-ray absorption, and resonance Raman spectroscopies and mass spectrometry supported a high-spin S = 5/2 Fe(III)… read more here.
Keywords: electrophilic reactivity; iii; peroxo; reactivity ... See more keywords
Investigation of the electrophilic reactivity of the biologically active marine sesquiterpenoid onchidal and model compounds
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DOI: 10.3762/bjoc.14.197
Abstract: The structure of the sesquiterpene onchidal (6), a component of the defensive secretion of the shell-less mollusc Onchidella binneyi, contains a masked α,β-unsaturated 1,4-dialdehyde moiety, the presence of which has been proposed to be the… read more here.
Keywords: electrophilic reactivity; reactivity biologically; reactivity; model ... See more keywords