Synergistic Catalyst-Mediator Pairings for Electroreductive Cross-Electrophile Coupling Reactions.
Sign Up to like & getrecommendations! Published in 2022 at "ACS catalysis"
DOI: 10.1021/acscatal.1c05144
Abstract: Electroreductive cross-electrophile coupling (eXEC) represents an attractive approach for the direct C-C coupling of two electrophiles but generally suffers from limited scope compared to reactions with chemical reductants. This work demonstrates that mediator-assisted electrocatalysis is… read more here.
Keywords: catalyst mediator; mediator; electroreductive cross; electrophile coupling ... See more keywords
Nickel-catalyzed enantioselective electroreductive cross-couplings
Sign Up to like & getrecommendations! Published in 2020 at "Organic chemistry frontiers"
DOI: 10.1039/d0qo00901f
Abstract: Ni-Catalyzed reductive cross-coupling of two electrophiles has recently evolved into a powerful means for building diverse carbon–carbon bonds in an enantioselective manner. However, this strategy usually requires the use of excessive metal powder as a… read more here.
Keywords: cross couplings; enantioselective electroreductive; electroreductive cross; cross ... See more keywords