Electrostatic vs. inductive effects in phosphine ligand donor properties and reactivity
Sign Up to like & getrecommendations! Published in 2022 at "Chemical Science"
DOI: 10.1039/d1sc04277g
Abstract: Enhanced rates and selectivity in enzymes are enabled in part by precisely tuned electric fields within active sites. Analogously, the use of charged groups to leverage electrostatics in molecular systems is a promising strategy to… read more here.
Keywords: inductive effects; donor; electrostatic inductive; donor strength ... See more keywords