Phosphinine Selenide: Noncovalent Interactions with Organoiodines and Elemental Iodine, and Reactivity towards Potassium Cyanide.
Sign Up to like & getrecommendations! Published in 2023 at "ChemPlusChem"
DOI: 10.1002/cplu.202300088
Abstract: Invited for this month's cover is the group of Prof. Dr. Christian Müller from Freie Universität Berlin, Germany. The cover picture shows a phosphinine selenide that interacts with organoiodines and halogens to form co-crystalline and… read more here.
Keywords: elemental iodine; phosphinine selenide; noncovalent interactions; selenide noncovalent ... See more keywords
Elemental iodine mediated synthesis of thiadiazole-based dithiafulvalene donors via C(sp2)–S formation
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DOI: 10.1016/j.tetlet.2018.11.072
Abstract: Abstract A series of thiadiazole-based dithiafulvalene (DTF) derivatives has been synthesized in moderate yields via iodine-mediated oxidative vinylic C(sp2)–H sulfenylation with mercapto-thiadiazoles. The formation of C(sp2)–S bond was confirmed and characterized by NMR and single… read more here.
Keywords: iodine mediated; based dithiafulvalene; elemental iodine; thiadiazole based ... See more keywords
Dimerization of a mixed-carbene PdII dibromide complex by elemental iodine.
Sign Up to like & getrecommendations! Published in 2017 at "Acta crystallographica. Section C, Structural chemistry"
DOI: 10.1107/s2053229617016412
Abstract: A monomeric PdII complex bearing a mixed carbocyclic/N-heterocyclic carbene ligand and two bromides was reacted with an excess of elemental iodine, which resulted in the surprising removal of one bromide ligand and dimerization of the… read more here.
Keywords: carbene; mixed carbene; elemental iodine; dimerization mixed ... See more keywords