Multinuclear compounds of s-elements with sterically hindered о-semiquinonates and catecholates
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DOI: 10.1007/s11172-018-2038-2
Abstract: Alkali metals form mutinuclear compounds with redox-active singly and doubly reduced derivatives of sterically of hindered о-benzoquinones. Complexes [Na6(Cat)3(THF)7]•4THF, [Na5(Cat)2(SQ)(THF)5], [Na4(SQ)4(THF)4]•THF•C6H14, [Na4(3,5-SQ)4(THF)4], [K4(SQ)4(THF)4]•4THF and [Li3(SQ)3(THF)3]•THF (Cat is catecholate, SQ is semiquinonate) possessing high sensitivity to… read more here.
Keywords: elements sterically; thf thf; sterically hindered; thf ... See more keywords