Asymmetric Elimination Reaction on Chiral Metal Surfaces.
Sign Up to like & getrecommendations! Published in 2021 at "Advanced materials"
DOI: 10.1002/adma.202104481
Abstract: The production of enantiopure materials and molecules is of uttermost relevance in research and industry in numerous contexts, ranging from non-linear optics to asymmetric synthesis. In the context of the latter, we have investigated dehalogenation,… read more here.
Keywords: pdga 111; 111 surfaces; elimination reaction; reaction ... See more keywords
Synthesis, Structure, and Reductive Elimination of Cationic Monoarylpalladium(IV) Complexes Supported by a Tripodal Oxygen Ligand
Sign Up to like & getrecommendations! Published in 2017 at "European Journal of Inorganic Chemistry"
DOI: 10.1002/ejic.201700326
Abstract: Cationic monoaryl–PdIV complexes supported by the Klaui tripodal ligand [Co(η5-C5H5){P(O)(OEt)2}3]– (LOEt–) were synthesized, and their reductive elimination was studied. Treatment of trans-[Pd(PPh3)2(Ar)(I)] and [{Pd(η2-ppytBu)Cl}2] [ppytBuH = 2-(4-tert-butylphenyl)pyridine] with [AgLOEt] afforded [Pd(Ar)(PPh3)(η2-LOEt)] [Ar = Ph (1),… read more here.
Keywords: complexes supported; loet; elimination; loet pf6 ... See more keywords
Pivotal Neighboring-Group Participation in Substitution versus Elimination Reactions – Computational Evidence for Ion Pairs in the Thionation of Alcohols with Lawesson's Reagent
Sign Up to like & getrecommendations! Published in 2017 at "European Journal of Organic Chemistry"
DOI: 10.1002/ejoc.201700127
Abstract: The mechanism of the thionation of alcohols with Lawesson's reagent was explored through quantum chemical DFT methods. Evidence that carbocations are involved was found. The mechanism is completely different to that established recently for the… read more here.
Keywords: thionation; alcohols lawesson; lawesson reagent; thionation alcohols ... See more keywords
Elimination of cervical cancer in Tanzania: Modelled analysis of elimination in the context of endemic HIV infection and active HIV control
Sign Up to like & getrecommendations! Published in 2021 at "International Journal of Cancer"
DOI: 10.1002/ijc.33533
Abstract: The World Health Organisation (WHO) has launched a strategic initiative for cervical cancer (CC) elimination which involves scaling up three interventions: human papillomavirus (HPV) vaccination, twice‐lifetime HPV‐screening screening and pre‐cancer/cancer treatment by 2030. CC is… read more here.
Keywords: hpv screening; control; hiv; cancer ... See more keywords
Is hepatitis C virus elimination possible among people living with HIV and what will it take to achieve it?
Sign Up to like & getrecommendations! Published in 2018 at "Journal of the International AIDS Society"
DOI: 10.1002/jia2.25062
Abstract: The World Health Organization targets for hepatitis C virus (HCV) elimination include a 90% reduction in new infections by 2030. Our objective is to review the modelling evidence and cost data surrounding feasibility of HCV… read more here.
Keywords: virus elimination; among people; hepatitis virus; living hiv ... See more keywords
Hepatitis C virus elimination: time for disruptive innovation
Sign Up to like & getrecommendations! Published in 2019 at "Journal of the International AIDS Society"
DOI: 10.1002/jia2.25360
Abstract: As we take stock this World Hepatitis day, a mere 11 years from the World Health Organization’s (WHO) 2030 target date for global Hepatitis C Virus (HCV) elimination (a 90% reduction in new diagnoses and… read more here.
Keywords: disruptive innovation; hepatitis; health; hcv ... See more keywords
Mathematical modeling of the immune system response to pathogens
Sign Up to like & getrecommendations! Published in 2020 at "Mathematical Methods in the Applied Sciences"
DOI: 10.1002/mma.6532
Abstract: The detection and elimination of pathogens in an organism are the main tasks of its immune system. The most important cells involved in these processes are neutrophils and macrophages. These processes might have two resolutions:… read more here.
Keywords: system; elimination; system response; mathematical modeling ... See more keywords
Roaming‐Mediated CH2NH Elimination from the Ionization of Aromatic Ethylamines
Sign Up to like & getrecommendations! Published in 2017 at "ChemistryOpen"
DOI: 10.1002/open.201600144
Abstract: Abstract The ionization of aromatic ethylamines by photons or electrons leads to elimination of CH2NH fragments, supposedly deriving from the McLafferty rearrangement involving intramolecular γ‐hydrogen transfer. Using tryptamine and phenethylamine as examples, the results reported… read more here.
Keywords: ionization aromatic; ch2nh elimination; aromatic ethylamines; roaming mediated ... See more keywords
A New Perspective on Cryotherapy: Pathogen Elimination Using Plant Shoot Apical Meristem via Cryogenic Techniques.
Sign Up to like & getrecommendations! Published in 2020 at "Methods in molecular biology"
DOI: 10.1007/978-1-0716-0183-9_15
Abstract: Plant pathogens cause different diseases on crops and industrial plant species that result in economic losses. Pathogen-free plant material has usually been obtained by traditional procedures such as meristem culture, thermotherapy, and chemotherapy. However, there… read more here.
Keywords: plant; perspective cryotherapy; cryogenic; cryotherapy pathogen ... See more keywords
Urinary metabolites of the UV filter octocrylene in humans as biomarkers of exposure
Sign Up to like & getrecommendations! Published in 2019 at "Archives of Toxicology"
DOI: 10.1007/s00204-019-02408-7
Abstract: Octocrylene (OC) is a UV filter used in sun screens and other personal care products, but also in polymers and food contact materials for stabilization. In this study, we investigate human OC metabolism and urinary… read more here.
Keywords: metabolites filter; cpaa; elimination; filter octocrylene ... See more keywords
Delayed crises following benzodiazepine withdrawal: deficient adaptive mechanisms or simple pharmacokinetics? Detoxification assisted by serum-benzodiazepine elimination tracking.
Sign Up to like & getrecommendations! Published in 2021 at "European journal of clinical pharmacology"
DOI: 10.1007/s00228-021-03205-x
Abstract: OBJECTIVE Rapid relapses after successful withdrawal occur even in apparently motivated benzodiazepine (BZD)-dependent patients. Regardless of known personality or biological (re-adaptation) issues, the aim of this open-label, single-arm, seminaturalistic study was to search for any… read more here.
Keywords: benzodiazepine; detoxification; serum bzd; withdrawal ... See more keywords