Intimate relationship between C-I reductive elimination, aryl scrambling and isomerization processes in Au(III) complexes.
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DOI: 10.1039/d2cc06415d
Abstract: 19F NMR monitoring shows that heating trans-[AuIIIRf2I2]- solutions (Rf = C6F3Cl2-3,5) leads to formation of cis-[AuRf2I2]-, [AuRf3I]- and [AuRfI3]-via kinetic competition between isomerization and Rf/I scrambling. The system evolution is driven by the easy Rf-I… read more here.
Keywords: relationship reductive; isomerization; elimination aryl; reductive elimination ... See more keywords