Asymmetric Elimination Reaction on Chiral Metal Surfaces.
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DOI: 10.1002/adma.202104481
Abstract: The production of enantiopure materials and molecules is of uttermost relevance in research and industry in numerous contexts, ranging from non-linear optics to asymmetric synthesis. In the context of the latter, we have investigated dehalogenation,… read more here.
Keywords: pdga 111; 111 surfaces; elimination reaction; reaction ... See more keywords
Bioorthogonal Retro-Cope Elimination Reaction of N,N-Dialkylhydroxylamines and Strained Alkynes.
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DOI: 10.1021/jacs.1c00885
Abstract: A bioorthogonal reaction between N,N-dialkylhydroxylamines and cyclooctynes is described. This reaction features a highly regioselective transformation between small, easily functionalizable reaction components with second-order rate constants reaching 84 M-1 s-1. The reaction is orthogonal to… read more here.
Keywords: reaction dialkylhydroxylamines; cope elimination; elimination reaction; reaction ... See more keywords
Radical Allylation: E-Selective Radical Conjugate Addition–Elimination Reaction from Morita–Baylis–Hillman Adducts
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DOI: 10.1055/s-0036-1590922
Abstract: Triethylborane-mediated radical allylation was performed from Morita–Baylis–Hillman alcohols with no need of protecting group. The radical conjugated addition–elimination reaction is highly selective, and trisubstituted E-alkenes were obtained. This reaction opened a new route for the… read more here.
Keywords: morita baylis; radical allylation; baylis hillman; addition elimination ... See more keywords