Racemic Total Synthesis of Elmonin and Pratenone A, from Streptomyces, Using a Common Intermediate Prepared by peri-Directed C–H Functionalization
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DOI: 10.1021/acs.orglett.2c03449
Abstract: The first total synthesis of elmonin and pratenone A, two complex rearranged angucyclinones from Streptomyces, is reported. Using peri-directed C–H functionalization, the key naphthalene fragment present in both synthetic targets was efficiently prepared. Coupling to… read more here.
Keywords: directed functionalization; elmonin pratenone; total synthesis; peri directed ... See more keywords