Importance of Axial Symmetry in Elucidating Lanthanide-Transition Metal Interactions.
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DOI: 10.1021/acs.inorgchem.9b02064
Abstract: In this paper, we experimentally study and model the electron donating character of an axial diamagnetic Pd2+ ion in four metalloligated lanthanide complexes of formula [PPh4][Ln{Pd(SAc)4}2] (SAc- = thioacetate, Ln = Tb, Dy, Ho, and… read more here.
Keywords: axial symmetry; transition metal; lanthanide transition; symmetry elucidating ... See more keywords