Elucidation of Excited-State Properties of Bimetallic Ir(III)–Pt(II) Complexes with Conjugated Bridging Ligands
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DOI: 10.1021/acs.jpcc.8b06665
Abstract: We investigated excited-state properties of 4′,7′-phenanthrolino-5′,6′:2,3-pyrazine (ppz)-bridged bimetallic complexes, (L)2Ir-ppz-PtCl2 (Ir-ppz-Pt) (L = 2-(4′,6′-difluorophenyl)pyridinato-N,C2 (dfppy)), and [(L)2Ir]2(ppz) (Ir-ppz-Ir). These properties were compared to those of reported dpp bridging complexes, 2,3-bis(2-pyridyl)pyrazine (dpp)-bridged bimetallic complexes, Ir-dpp-Pt, and… read more here.
Keywords: state; elucidation excited; excited state; bridging ligands ... See more keywords