Elucidation of a Redox-Mediated Reaction Cycle for Nickel-Catalyzed Cross Coupling.
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DOI: 10.1021/jacs.8b11262
Abstract: A reaction cycle for redox-mediated, Ni-catalyzed aryl etherification is proposed under both photoredox and electrochemically mediated conditions. We demonstrate that a self-sustained Ni(I/III) cycle is operative in both cases by chemically synthesizing and characterizing a… read more here.
Keywords: cycle; elucidation redox; redox mediated; reaction cycle ... See more keywords