Synthesis, crystallographic and spectroscopic characterization, and theoretical elucidation of an elusive aminyl radical containing a CuII-aminyl-iminosemiquinone complex.
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DOI: 10.1039/d0cc07378d
Abstract: An elusive aminyl radical and an iminosemiquinone radical-coordinated square pyramidal Cu(ii) complex (1) have been isolated by the reaction between the noninnocent ligand H4LPy(AP) and Cu(ClO4)2ยท6H2O in the presence of Et3N and air as the… read more here.
Keywords: spectroscopic characterization; synthesis crystallographic; aminyl radical; elusive aminyl ... See more keywords