Cd(II) enantiomers embedding helices from 3D frameworks to 2D layers controlled by shapes of ancillary ligands
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DOI: 10.1080/00958972.2021.1898602
Abstract: Abstract Two pairs of chiral coordination polymers, [Cd2((R)-CBA)2(1,4-BMIB)]n (1-R ), [Cd2((R)-CBA)2(1,4-BMIB)]n (1-S ), {[Cd((R)-CBA)(1,3-BMIB)]·H2O}n (2-R ), and {[Cd((R)-CBA)(1,3-BMIB)]·H2O}n (2-S ) (H2CBA = 4-(1-carboxyethoxy) benzoic acid, 1,4-BMIB = 1,4-bis(2-methyl-1H-imidazol-1-yl)benzene, 1,3-BMIB = 1,3-bis(2-methyl-1H-imidazol-1-yl)benzene), were constructed from lactate… read more here.
Keywords: enantiomers embedding; embedding helices; shapes ancillary; bmib ... See more keywords