Formation of Ylidenehydrazines Enabled by Manganese-Catalyzed Acceptorless Dehydrogenative Coupling
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DOI: 10.1039/d3qo01890c
Abstract: Catalytic dehydrogenation, which exhibits highly atom-economical and chemo selective properties, converts multiple green sustainable alcohols to critical molecules and is a highly desirable and elusive process; furthermore, the dehydrogenation of... read more here.
Keywords: formation ylidenehydrazines; enabled manganese; acceptorless dehydrogenative; catalyzed acceptorless ... See more keywords
2-Pyridone-Enabled Manganese-Catalyzed ortho-Selective Deuteration of Aromatic Amides with D₂O
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DOI: 10.1039/d5qo00606f
Abstract: We present a highly efficient and regioselective methodology for the synthesis of ortho-deuterated aromatic amides, utilizing Mn(CO)₅Br as the catalyst, 2-pyridone as the CMD base, and D₂O as the deuterium... read more here.
Keywords: enabled manganese; catalyzed ortho; manganese catalyzed; pyridone enabled ... See more keywords