Synthesis of vitisin A & D enabled by a persistent radical equilibrium.
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DOI: 10.1021/jacs.0c01714
Abstract: The first total synthesis of the resveratrol tetramers vitisin A and vitisin D is reported. Electrochemical generation and selective dimerization of persistent radicals is followed by thermal isomerization of the symmetric C8b-C8c dimer to the… read more here.
Keywords: vitisin; synthesis vitisin; persistent radical; enabled persistent ... See more keywords