Ligand-Enabled β-C(sp3)-H Olefination of Free Carboxylic Acids.
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DOI: 10.1021/jacs.8b06527
Abstract: An acetyl-protected aminoethyl phenyl thioether has been developed to promote C(sp3)-H activation. Significant ligand enhancement is demonstrated by the realization of the first Pd(II)-catalyzed olefination of C(sp3)-H bonds of free carboxylic acids without using an… read more here.
Keywords: sp3 olefination; free carboxylic; enabled sp3; carboxylic acids ... See more keywords