1,2-Azide Migration Enables Synthesis of β-Difluoroalkyl Azides
Sign Up to like & getrecommendations! Published in 2020 at "Chem"
DOI: 10.1016/j.chempr.2020.01.016
Abstract: Reactions involving an azido group where the azide remains intact are rare and largely underexplored. In this issue of Chem, Bi and co-workers disclose a mild, functional-group-tolerant strategy for the synthesis of β-difluoroalkyl azides from… read more here.
Keywords: synthesis difluoroalkyl; migration enables; difluoroalkyl azides; enables synthesis ... See more keywords
Organophotocatalysis Enables the Synthesis of gem-Fluorophosphonate Alkenes.
Sign Up to like & getrecommendations! Published in 2022 at "Organic letters"
DOI: 10.1021/acs.orglett.2c03366
Abstract: gem-Bromofluoroalkenes have been combined with phosphite under irradiation, in the presence of Fukuzumi's catalyst (9-mesityl-10-methylacridinium perchlorate) as an organic photocatalyst, to provide valuable gem-fluorophosphonate derivatives, known as stable mimics of phosphates. The desired products were… read more here.
Keywords: gem; enables synthesis; gem fluorophosphonate; organophotocatalysis enables ... See more keywords