Enabling Reductive C-N Cross-Coupling of Nitroalkanes and Boronic Acids by Steric Design of P(III)/P(V)═O Catalysts.
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DOI: 10.1021/jacs.2c01487
Abstract: An organophosphorus-catalyzed C-N bond-forming reductive coupling of nitroalkanes with arylboronic acids and esters is reported. The method shows excellent chemoselectivity for the nitro/boronic acid substrate pair, allowing the synthesis of N-(hetero)arylamines rich in functionalization. The… read more here.
Keywords: boronic acids; enabling reductive; coupling nitroalkanes; reductive cross ... See more keywords