Cobaloxime Catalysis for Enamine Phosphorylation with Hydrogen Evolution.
Sign Up to like & getrecommendations! Published in 2020 at "Organic letters"
DOI: 10.1021/acs.orglett.0c01709
Abstract: Direct phosphorylation of enamine and enamide with hydrogen evolution was realized via cobaloxime catalysis under visible-light irradiation. Control experiments and spectroscopic studies demonstrated a reductive quenching pathway of cobaloxime catalyst to produce phosphinoyl radical, which… read more here.
Keywords: phosphorylation; hydrogen evolution; cobaloxime catalysis; enamine ... See more keywords
Enamine Approach for Versatile and Reversible Functionalization on Cellulose Related Porous Sponges
Sign Up to like & getrecommendations! Published in 2018 at "ACS Sustainable Chemistry & Engineering"
DOI: 10.1021/acssuschemeng.8b01369
Abstract: A readily modifiable cellulose sponge was prepared from cellulose acetoacetate (CAA). Facile postsynthetic modification with primary amino-containing modifiers such as octadecyl amine (ODA), cysteine (CYS), and l-glutamic acid (GLU) could be achieved demonstrating the ease… read more here.
Keywords: postsynthetic modification; enamine bonds; approach versatile; enamine approach ... See more keywords