A Cobalt-Catalyzed Enantioconvergent Radical Negishi C(sp3)–C(sp2) Cross-Coupling with Chiral Multidentate N,N,P-Ligand
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DOI: 10.1021/acs.organomet.1c00190
Abstract: A cobalt-catalyzed enantioconvergent radical Negishi C(sp)−C(sp) cross-coupling of racemic benzyl chlorides with arylzinc reagents has been developed in good yield with moderate enantioselectivities. This strategy provides an expedient access toward a range of enantioenriched 1,1-diarylmethanes.… read more here.
Keywords: enantioconvergent cross; cross coupling; cross; catalyzed enantioconvergent ... See more keywords