Preparation of Enantioenriched Alkylcarbastannatranes via Nucleophilic Inversion of Alkyl Mesylates for Use in Stereospecific Cross-Coupling Reactions.
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DOI: 10.1021/acs.organomet.9b00467
Abstract: We report the preparation of enantioenriched secondary alkylcarbastannatranes via a stereoinvertive SN2 reaction of enantioenriched alkyl mesylates and carbastannatranyl anion equivalents. Using this process, enantioenriched secondary alcohols may be converted into highly enantioenriched alkylcarbastannatranes, which… read more here.
Keywords: alkyl mesylates; enantioenriched alkylcarbastannatranes; stereospecific cross; alkylcarbastannatranes via ... See more keywords