Nickel-Catalyzed Asymmetric C-Alkylation of Nitroalkanes: Synthesis of Enantioenriched β-Nitroamides.
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DOI: 10.1021/jacs.9b04175
Abstract: A general catalytic method for asymmetric C-alkylation of nitroalkanes using nickel catalysis is described. This method enables the formation of highly enantioenriched β-nitroamides from readily available α-bromoamides using mild reaction conditions that are compatible with… read more here.
Keywords: catalyzed asymmetric; asymmetric alkylation; enantioenriched nitroamides; nickel catalyzed ... See more keywords