Enantiomeric discrimination by chiral electromagnetic resonance enhancement.
Sign Up to like & getrecommendations! Published in 2023 at "Chirality"
DOI: 10.1002/chir.23578
Abstract: Circularly polarized light interacts preferentially with the biomolecules to generate spectral fingerprints reflecting their primary and secondary structure in the ultraviolet region of the electromagnetic spectrum. The spectral features can be transferred to the visible… read more here.
Keywords: discrimination chiral; enantiomeric discrimination; discrimination; resonance enhancement ... See more keywords
Direct enantiomeric discrimination through antisymmetric hyperfine coupling.
Sign Up to like & getrecommendations! Published in 2021 at "Chemical communications"
DOI: 10.1039/d1cc02579a
Abstract: Chiral open-shell molecules possessing permanent electric dipole moments have an EPR signal at the difference frequency of the electron and nuclear resonances, allowing direct enantiomeric discrimination by signal phase. The effect depends on the vector… read more here.
Keywords: direct enantiomeric; enantiomeric discrimination; hyperfine coupling; discrimination antisymmetric ... See more keywords
Enantiomeric Discrimination in Insects: The Role of OBPs and ORs
Sign Up to like & getrecommendations! Published in 2022 at "Insects"
DOI: 10.3390/insects13040368
Abstract: Simple Summary Insects use olfaction, i.e., their sense of smell, to detect odors that elicit behavioral responses, with structurally similar compounds eliciting different responses. The roles of specific recognition proteins, i.e., odorant-binding proteins (OBPs) and… read more here.
Keywords: insects; enantiomeric discrimination; discrimination; role obps ... See more keywords