Manganes-Porphyrin as Efficient Enantioselective Catalyst for Aerobic Epoxidation of Olefins
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DOI: 10.1007/s10562-018-2447-8
Abstract: A chiral manganese porphyrin, [Mn(TCPP-Ind)Cl], was synthesized using cis-1-amino-2-indanol substituent. It showed remarkable catalytic activity and enantioselectivity in the epoxidation of olefins with O2/RCHO. Terminal olefins and styrene derivatives were successfully oxidized (> 99% ee). TON… read more here.
Keywords: manganes porphyrin; efficient enantioselective; epoxidation; enantioselective catalyst ... See more keywords