Diastereoselective and Enantioselective Conjunctive Cross-Coupling Enabled by Boron Ligand Design.
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DOI: 10.1021/jacs.8b09909
Abstract: Enantio- and diastereoselective conjunctive cross-coupling of β-substituted alkenylboron "ate" complexes is studied. Whereas β-substitution shifts the chemoselectivity of the catalytic reaction in favor of the Suzuki-Miyaura product, use of a boronic ester ligand derived from… read more here.
Keywords: conjunctive cross; enantioselective conjunctive; diastereoselective enantioselective; ligand ... See more keywords