Alkyne Hydroheteroarylation: Enantioselective Coupling of Indoles and Alkynes via Rh-Hydride Catalysis.
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DOI: 10.1021/jacs.7b05893
Abstract: We report an enantioselective coupling between alkynes and indoles. A Rh-hydride catalyst isomerizes alkynes to generate a metal-allyl species that can be trapped with both aromatic and heteroaromatic nucleophiles. read more here.
Keywords: enantioselective coupling; indoles alkynes; hydroheteroarylation enantioselective; coupling indoles ... See more keywords
Photoinduced copper-catalyzed enantioselective coupling reactions.
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DOI: 10.1039/d2cs00734g
Abstract: Copper-catalyzed enantioselective coupling has been widely investigated, which allows rapid construction of various chiral molecules. Despite important advances via polar and radical mechanisms, exploring general and practical strategies for the regio-, enantio- and diastereoselective assembly… read more here.
Keywords: copper; enantioselective coupling; copper catalyzed; photoinduced copper ... See more keywords