Enantioselective Folding of Enynes by Gold(I) Catalysts with a Remote C2-Chiral Element.
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DOI: 10.1021/jacs.9b06326
Abstract: Chiral gold(I) catalysts have been designed based on a modified JohnPhos ligand with a distal C2-2,5-diarylpyrrolidine that creates a tight binding cavity. The C2-chiral element is close to where the C-C bond formation takes place… read more here.
Keywords: enantioselective folding; chiral element; gold catalysts;