Enantioselective Mannich Reaction Employing 1,3,5‐Triaryl‐1,3,5‐triazinanes Catalyzed by Chiral‐at‐Metal Rhodium Complexes
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DOI: 10.1002/ejoc.201700463
Abstract: Chiral-at-metal Rh(III) complexes catalyzed highly efficient enantioselective Mannich reaction of 2-acyl imidazoles with 1,3,5-triazinanes is developed, affording the corresponding adducts in 81-99% yields with up to >99% enantioselectivities. This protocol performs with 0.1 mol %… read more here.
Keywords: chiral metal; enantioselective mannich; mannich reaction; reaction employing ... See more keywords