Silver-Catalyzed Direct Nucleophilic Cyclization: Enantioselective De Novo Synthesis of C-C Axially Chiral 2-Arylindoles.
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DOI: 10.1021/acs.orglett.2c04234
Abstract: Atropisomeric indoles widely exist in natural products, pharmaceuticals, functional materials, and catalysts for their featured biological activities, photoelectric properties, and catalytic activities, while facile and de novo construction of this motif remains underexplored. Herein, we… read more here.
Keywords: enantioselective novo; nucleophilic cyclization; chiral arylindoles; catalyzed direct ... See more keywords