Enantioseparation of P-Stereogenic 1-Adamantyl Arylthiophosphonates and Their Stereospecific Transformation to 1-Adamantyl Aryl-H-phosphinates
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DOI: 10.3390/molecules28041584
Abstract: A focused library of 1-adamantyl arylthiophosphonates was prepared in racemic form. An enantioseparation method was developed for P-stereogenic thiophosphonates using (S)-1-phenylethylamine as the resolving agent. Under optimized conditions, three out of the five arylthiophosphonates were… read more here.
Keywords: adamantyl arylthiophosphonates; stereogenic adamantyl; adamantyl aryl; enantioseparation stereogenic ... See more keywords